Syllabus (CHEMISTRY)

Course Type: ME-8

Semester: 7

Course Code: BCEMMEB47C

Course Title: Inorganic & Physical Chemistry–II

(L-P-Tu): 3-1-0

Credit: 4

Practical/Theory: Combined

Course Objective: COURSE OBJECTIVE OF MINOR - 8: The syllabus of Minor -8 has been designed to provide the students with the concept of Redox reactions will provide the fundamental understandings of chemistry, inevitable for higher learning.

Learning Outcome: COURSE OUTCOMES OF MINOR – 8: CO- 8.1: Understand the concepts of a redox reaction. CO- 8.2: Explain various phenomenon of redox reactions using Nernst Equation. CO- 8.3: The syllabus of this module has been designed to provide the students with in

THEORY:

1. REDOX (10 L):

Balancing of equations by oxidation number and ion-electron method oxidimetry and reductimetry.

2. Group Chemistry (s & p- block only) (20 L):

a.Group trends in electronic configuration, modification of pure elements,common oxidation states, inert pair effect, and their important compounds in respect of the following groups of elements:
i. B-Al-Ga-In-Tl

ii. C-Si-Ge-Sn-Pb

iii. N-P-As-Sb-Bi

iv. O-S-Se-Te

v. F-Cl-Br-I

3. Thermodynamics-I (15 L):

1. Zeroth and 1st law of Thermodynamics: Intensive and extensive variables; stateand path functions; isolated, closed and open systems; zeroth law ofthermodynamics; Concept of heat, work, internal energy and statement of firstlaw; enthalpy, H; relation between heat capacities, calculations of q, w, U and H for reversible, irreversible and free expansion of gases (ideal and van der Waals) under isothermal and adiabatic conditions; Joule’s experiment and its consequence.

READING REFERENCES:

1. Misra, S.; Giri, G. C.; Roy, S. K.; Chanda, G., SnatakRasayan, B.Sc. Semester-I, II, III, IV, Santra Publication.

2. Physical Chemistry, P. C. Rakshit, Sarat Book House, Kolkata.

3. Physical Chemistry, Hrishikesh Chatterjee, Vol. 1-2, Platinum Publishers.

4. Lee, J. D. Concise Inorganic Chemistry ELBS, 1991.

5. R. P. Sarkar, General and Inorganic Chemistry, Part-1 & 2, New Central Book Agency (P) Ltd. Kolkata.

PRACTICALS:

Qualitative semi-micro analysis of mixture containing three radicals.

Acid Radicals: Cl-, Br-, I-, NO2-, NO3-, S2-, SO42-, PO43-, BO33-, H3BO3.

Basic Radicals: Na+, K+, Ca2+, Sr2+, Ba2+, Cr3+, Mn2+, Fe3+, Ni2+, Cu2+, NH4+.

REFERENCES FOR PRACTICALS:

1. Svehla, G., Vogel’s Qualitative Inorganic Analysis, Pearson Education, 2012.
2. Mukherjee, G. N., Semi-Micro Qualitative Inorganic Analysis, University of Calcutta, 2008.
3. Bhattacharya, R. C., A Manual of Practical Chemistry for degree classes (Vol. I & II) for Honours Students, Biswas Book Stall, Calcutta.
4. A. K. Nad, B. Mahapatra, A. Ghoshal, An Advance Course in Practical Chemistry, New Central Book Agency (P) Ltd. Kolkata.

5. S. P. Dey, SnatakParikhyagareRasayan, Vol-I, Santra Publication, Kolkata.